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Molecular Ru and Ir Complexes Capable of Acting as Water Oxidation Catalysts
BOOK CHAPTER In: "Molecular Solar Fuels", Ed. T. J. Wydrzynski, W. Hillier. RSC Publishing, London, 2012, 10, 273-287, (ISBN: 978-1-84973-034-1) -
Cobalt analogs of Ru-based water oxidation catalysts: Overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution
Chem. Sci. 2012, 3, 3058-3062. -
Transition-metal complexes containing the dinucleating tetra-N-dentate 3,5-bis(2-pyridyl)pyrazole (Hbpp) ligand – A robust scaffold for multiple applications including the catalytic oxidation of water to molecular oxygen
COVER Eur. J. Inorg. Chem. 2012, 4775-4789. -
Organometallic iridium catalysts based on pyridinecarboxylate ligands for the oxidative splitting of water
Organometallics 2012, 31, 8071-8074. -
Catalytic four-electron reduction of O2 via rate-determining proton-coupled electron transfer to a dinuclear cobalt-μ-1,2-peroxo complex
J. Am. Chem. Soc. 2012, 134, 9906-9909. -
Ligand geometry directs O-O bond-formation pathway in ruthenium-based water oxidation catalyst
Angew. Chem. Int. Ed. 2012, 51, 5967-5970. -
Experimental and quantum chemical characterization of the water oxidation cycle catalysed by [RuII(damp)(bpy)(H2O)]2+
Chem. Sci. 2012, 3, 2576-2586. -
A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II
Nat. Chem. 2012, 4, 418-423.*This paper holds the third position in the Top 10 articles published in Nature Chemistry in 2012
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Substitution reactions in dinuclear Ru-Hbpp complexes: An evaluation of through-space interactions
Inorg. Chem. 2012, 51, 1889-1901. -
Synthesis, structure, and electronic properties of RuN6 dinuclear Ru-Hbpp complexes
Inorg. Chem. 2012, 51, 320-327.