A thermodynamically controlled resolution has allowed for the generation of diastereomerically enriched complexes, by chirality transfer from an enantiopure building block to a dynamically racemic biaryl derivative. A switchable sense of induction could be achieved depending on the substituents of the chiral block.
Supramolecular-directed chiral induction in biaryl derivatives
J. Org. Chem. 2009, 74, 8794-8797.