A novel decahydrodecaborate-functionalized Anderson type polyoxometalate has been synthesized and characterized in solution by ESI-MS, various NMR techniques and electrochemical methods. DFT studies provide strong support to understand the properties of this hybrid system.
Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate
Dalton Trans. 2020, 49, 4685-4689, DOI: 10.1039/C9DT04676C.